Animated Periodic Table

Arsenic (As)

Arsenic is element 33, a metalloid in group 15, period 4. A neutral atom has 33 protons, 42 neutrons and 33 electrons, 5 of them valence electrons.

Metalloid
Atomic number
33
Atomic mass
74.922 u
Valence electrons
5
Protons · neutrons
33 · 42
Electrons per shell
2, 8, 18, 5
At room temperature
solid
Bohr model of Arsenic: 33 protons and 42 neutrons in the nucleus; electrons by shell 2, 8, 18, 5
Protons ● · neutrons ● · valence electrons ●

Bohr model of arsenic

The Bohr model draws arsenic as a nucleus of 33 protons and 42 neutrons, with its 33 electrons on 4 circular shells: 2 in shell 1, 8 in shell 2, 18 in shell 3, 5 in shell 4. Press Build the atom to watch the shells fill from the inside out. The outer ring (the N shell) is dashed: the electrons there are the ones that take part in chemistry.

Real electrons don't travel in neat circles. They live in fuzzy orbitals, shown below, but the Bohr picture is the quickest way to count shells and valence electrons.

Electron configuration of arsenic

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p³

Short form (noble gas notation): [Ar] 4s² 3d¹⁰ 4p³. The [Ar] stands for the electrons of argon, the noble gas before it.

Orbital diagram — each box is one orbital holding up to two electrons with opposite spins (↑↓). Within a subshell, every box gets one electron before any gets a second (Hund's rule).
↑↓1s2
↑↓2s2
↑↓↑↓↑↓2p6
↑↓3s2
↑↓↑↓↑↓3p6
↑↓4s2
↑↓↑↓↑↓↑↓↑↓3d10
↑↑↑4p3

How many valence electrons does arsenic have?

Arsenic has 5 valence electrons.

Arsenic is in group 15, and for groups 13–18 you subtract 10 from the group number: 15 − 10 = 5. It tends to share electrons in covalent bonds.

Protons, neutrons and electrons

Protons33equal to the atomic number
Electrons33equal to the protons in a neutral atom
Neutrons42mass number 75 − 33 protons

Atoms of the same element can have different numbers of neutrons (isotopes). The count above uses the rounded atomic mass, the way it's taught in class.

Arsenic properties

SymbolAs
CategoryMetalloid
Group · period · block15 · 4 · p
Atomic mass74.922 u
State at 25 °Csolid
Melting point1,090 K (817 °C, 1,500 °F)
Boiling point887 K (614 °C, 1,140 °F)
Density5.776 g/cm³
Electronegativity (Pauling)2.18
Atomic radius185 pm
First ionization energy9.815 eV
Electron affinity0.81 eV
Oxidation states+5, +3, −3
Common ion charge+5, +3
DiscoveredKnown since ancient times

Where arsenic sits on the periodic table

Group 15: Nitrogen, Phosphorus, Antimony, Bismuth, Moscovium.

Questions about arsenic

How many valence electrons does arsenic have?

Arsenic has 5 valence electrons.

How many protons, neutrons and electrons does arsenic have?

A neutral arsenic atom has 33 protons and 33 electrons. Its most common form has about 42 neutrons (mass number 75 − 33 protons).

What is the electron configuration of arsenic?

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p³, written in short form as [Ar] 4s² 3d¹⁰ 4p³.

What does the Bohr model of arsenic look like?

A nucleus of 33 protons and 42 neutrons, circled by 4 electron shells holding 2, 8, 18, 5 electrons.

What is the atomic number of arsenic?

33. The atomic number is the number of protons in the nucleus, and it is what makes an atom arsenic.