Animated Periodic Table

Chlorine (Cl)

Chlorine is element 17, a halogen in group 17, period 3. A neutral atom has 17 protons, 18 neutrons and 17 electrons, 7 of them valence electrons.

Halogen
Atomic number
17
Atomic mass
35.45 u
Valence electrons
7
Protons · neutrons
17 · 18
Electrons per shell
2, 8, 7
At room temperature
gas
Bohr model of Chlorine: 17 protons and 18 neutrons in the nucleus; electrons by shell 2, 8, 7
Protons ● · neutrons ● · valence electrons ●

Bohr model of chlorine

The Bohr model draws chlorine as a nucleus of 17 protons and 18 neutrons, with its 17 electrons on 3 circular shells: 2 in shell 1, 8 in shell 2, 7 in shell 3. Press Build the atom to watch the shells fill from the inside out. The outer ring (the M shell) is dashed: the electrons there are the ones that take part in chemistry.

Real electrons don't travel in neat circles. They live in fuzzy orbitals, shown below, but the Bohr picture is the quickest way to count shells and valence electrons.

Electron configuration of chlorine

1s² 2s² 2p⁶ 3s² 3p⁵

Short form (noble gas notation): [Ne] 3s² 3p⁵. The [Ne] stands for the electrons of neon, the noble gas before it.

Orbital diagram — each box is one orbital holding up to two electrons with opposite spins (↑↓). Within a subshell, every box gets one electron before any gets a second (Hund's rule).
↑↓1s2
↑↓2s2
↑↓↑↓↑↓2p6
↑↓3s2
↑↓↑↓↑3p5

How many valence electrons does chlorine have?

Chlorine has 7 valence electrons.

Chlorine is in group 17, and for groups 13–18 you subtract 10 from the group number: 17 − 10 = 7. It tends to gain 1 electron to complete an octet, forming a −1 ion.

Protons, neutrons and electrons

Protons17equal to the atomic number
Electrons17equal to the protons in a neutral atom
Neutrons18mass number 35 − 17 protons

Atoms of the same element can have different numbers of neutrons (isotopes). The count above uses the rounded atomic mass, the way it's taught in class.

Chlorine properties

SymbolCl
CategoryHalogen
Group · period · block17 · 3 · p
Atomic mass35.45 u
State at 25 °Cgas
Melting point171.7 K (-101 °C, -151 °F)
Boiling point239.1 K (-34 °C, -29.3 °F)
Density0.0032 g/cm³
Electronegativity (Pauling)3.16
Atomic radius175 pm
First ionization energy12.968 eV
Electron affinity3.617 eV
Oxidation states+7, +5, +1, −1
Common ion charge−1
Discovered1774 by Carl Wilhelm Scheele

Where chlorine sits on the periodic table

Group 17: Fluorine, Bromine, Iodine, Astatine, Tennessine.

Questions about chlorine

How many valence electrons does chlorine have?

Chlorine has 7 valence electrons.

How many protons, neutrons and electrons does chlorine have?

A neutral chlorine atom has 17 protons and 17 electrons. Its most common form has about 18 neutrons (mass number 35 − 17 protons).

What is the electron configuration of chlorine?

1s² 2s² 2p⁶ 3s² 3p⁵, written in short form as [Ne] 3s² 3p⁵.

What does the Bohr model of chlorine look like?

A nucleus of 17 protons and 18 neutrons, circled by 3 electron shells holding 2, 8, 7 electrons.

What is the atomic number of chlorine?

17. The atomic number is the number of protons in the nucleus, and it is what makes an atom chlorine.